High-capacity hydrogen and nitric oxide adsorption and storage in a metal-organic framework

Bo Xiao; Paul S Wheatley; Xuebo Zhao; Ashleigh J Fletcher; Sarah Fox; Adriano G Rossi; Ian L Megson; S Bordiga; L Regli; K Mark Thomas; Russell E Morris

doi:10.1021/ja066098k

High-capacity hydrogen and nitric oxide adsorption and storage in a metal-organic framework

Bo Xiao
, Paul S Wheatley
, Xuebo Zhao
, Ashleigh J Fletcher
, Sarah Fox
, Adriano G Rossi
, Ian L Megson
, S Bordiga
, L Regli
, K Mark Thomas
, Russell E Morris

Research output: Contribution to journal › Article › peer-review

566 Citations (Scopus)

Abstract

Gas adsorption experiments have been carried out on a copper benzene tricarboxylate metal-organic framework material, HKUST-1. Hydrogen adsorption at 1 and 10 bar (both 77 K) gives an adsorption capacity of 11.16 mmol H2 per g of HKUST-1 (22.7 mg g(-)1, 2.27 wt %) at 1 bar and 18 mmol per g (36.28 mg g(-)1, 3.6 wt %) at 10 bar. Adsorption of D2 at 1 bar (77 K) is between 1.09 (at 1 bar) and 1.20(at

Original language	English
Pages (from-to)	1203-9
Number of pages	7
Journal	Journal of the American Chemical Society
Volume	129
Issue number	5
DOIs	https://doi.org/10.1021/ja066098k
Publication status	Published - 2007

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title = "High-capacity hydrogen and nitric oxide adsorption and storage in a metal-organic framework",

abstract = "Gas adsorption experiments have been carried out on a copper benzene tricarboxylate metal-organic framework material, HKUST-1. Hydrogen adsorption at 1 and 10 bar (both 77 K) gives an adsorption capacity of 11.16 mmol H2 per g of HKUST-1 (22.7 mg g(-)1, 2.27 wt \%) at 1 bar and 18 mmol per g (36.28 mg g(-)1, 3.6 wt \%) at 10 bar. Adsorption of D2 at 1 bar (77 K) is between 1.09 (at 1 bar) and 1.20(at ",

author = "Bo Xiao and Wheatley, \{Paul S\} and Xuebo Zhao and Fletcher, \{Ashleigh J\} and Sarah Fox and Rossi, \{Adriano G\} and Megson, \{Ian L\} and S Bordiga and L Regli and Thomas, \{K Mark\} and Morris, \{Russell E\}",

year = "2007",

doi = "10.1021/ja066098k",

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volume = "129",

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journal = "Journal of the American Chemical Society",

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T1 - High-capacity hydrogen and nitric oxide adsorption and storage in a metal-organic framework

AU - Xiao, Bo

AU - Wheatley, Paul S

AU - Zhao, Xuebo

AU - Fletcher, Ashleigh J

AU - Fox, Sarah

AU - Rossi, Adriano G

AU - Megson, Ian L

AU - Bordiga, S

AU - Regli, L

AU - Thomas, K Mark

AU - Morris, Russell E

PY - 2007

Y1 - 2007

N2 - Gas adsorption experiments have been carried out on a copper benzene tricarboxylate metal-organic framework material, HKUST-1. Hydrogen adsorption at 1 and 10 bar (both 77 K) gives an adsorption capacity of 11.16 mmol H2 per g of HKUST-1 (22.7 mg g(-)1, 2.27 wt %) at 1 bar and 18 mmol per g (36.28 mg g(-)1, 3.6 wt %) at 10 bar. Adsorption of D2 at 1 bar (77 K) is between 1.09 (at 1 bar) and 1.20(at

AB - Gas adsorption experiments have been carried out on a copper benzene tricarboxylate metal-organic framework material, HKUST-1. Hydrogen adsorption at 1 and 10 bar (both 77 K) gives an adsorption capacity of 11.16 mmol H2 per g of HKUST-1 (22.7 mg g(-)1, 2.27 wt %) at 1 bar and 18 mmol per g (36.28 mg g(-)1, 3.6 wt %) at 10 bar. Adsorption of D2 at 1 bar (77 K) is between 1.09 (at 1 bar) and 1.20(at

U2 - 10.1021/ja066098k

DO - 10.1021/ja066098k

M3 - Article

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SN - 0002-7863

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SP - 1203

EP - 1209

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 5

ER -

High-capacity hydrogen and nitric oxide adsorption and storage in a metal-organic framework

Abstract

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