High-capacity hydrogen and nitric oxide adsorption and storage in a metal-organic framework

Bo Xiao, Paul S Wheatley, Xuebo Zhao, Ashleigh J Fletcher, Sarah Fox, Adriano G Rossi, Ian L Megson, S Bordiga, L Regli, K Mark Thomas, Russell E Morris

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433 Citations (Scopus)

Abstract

Gas adsorption experiments have been carried out on a copper benzene tricarboxylate metal-organic framework material, HKUST-1. Hydrogen adsorption at 1 and 10 bar (both 77 K) gives an adsorption capacity of 11.16 mmol H2 per g of HKUST-1 (22.7 mg g(-)1, 2.27 wt %) at 1 bar and 18 mmol per g (36.28 mg g(-)1, 3.6 wt %) at 10 bar. Adsorption of D2 at 1 bar (77 K) is between 1.09 (at 1 bar) and 1.20(at
Original languageEnglish
Pages (from-to)1203-9
Number of pages7
JournalJournal of the American Chemical Society
Volume129
Issue number5
DOIs
Publication statusPublished - 2007

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    Xiao, B., Wheatley, P. S., Zhao, X., Fletcher, A. J., Fox, S., Rossi, A. G., Megson, I. L., Bordiga, S., Regli, L., Thomas, K. M., & Morris, R. E. (2007). High-capacity hydrogen and nitric oxide adsorption and storage in a metal-organic framework. Journal of the American Chemical Society, 129(5), 1203-9. https://doi.org/10.1021/ja066098k