Automation of flow injection gas diffusion-ion chromatography for the nanomolar determination of methylamines and ammonia in seawater and atmospheric samples

Stuart l Gibb; J W Wood; R Fauzi; C Mantoura

doi:10.1155/S1463924695000320

Automation of flow injection gas diffusion-ion chromatography for the nanomolar determination of methylamines and ammonia in seawater and atmospheric samples

Stuart l Gibb, J W Wood, R Fauzi, C Mantoura

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

The automation and improved design and performance of Flow Injection Gas Diffusion-Ion Chromatography (FIGD-IC), a novel technique for the simultaneous analysis of trace ammonia (NH(3)) and methylamines (MAs) in aqueous media, is presented. Automated Flow Injection Gas Diffusion (FIGD) promotes the selective transmembrane diffusion of MAs and NH(3) from aqueous sample under strongly alkaline (pH > 12, NaOH), chelated (EDTA) conditions into a recycled acidic acceptor stream. The acceptor is then injected onto an ion chromatograph where NH(3) and the MAs are fully resolved as their cations and detected conductimetrically. A versatile PC interfaced control unit and data capture unit (DCU) are employed in series to direct the selonoid valve switching sequence, IC operation and collection of data. Automation, together with other modifications improved both linearily (R(2) > 0.99 MAs 0-100 nM, NH(3) 0-1000 nM) and precision (

Original language	English
Pages (from-to)	205-212
Number of pages	8
Journal	The Journal of automatic chemistry
Volume	17
Issue number	6
DOIs	https://doi.org/10.1155/S1463924695000320
Publication status	Published - May 1995

Access to Document

10.1155/S1463924695000320

Cite this

@article{fe4d75d2fd59423f910269e8689d68a4,

title = "Automation of flow injection gas diffusion-ion chromatography for the nanomolar determination of methylamines and ammonia in seawater and atmospheric samples",

abstract = "The automation and improved design and performance of Flow Injection Gas Diffusion-Ion Chromatography (FIGD-IC), a novel technique for the simultaneous analysis of trace ammonia (NH(3)) and methylamines (MAs) in aqueous media, is presented. Automated Flow Injection Gas Diffusion (FIGD) promotes the selective transmembrane diffusion of MAs and NH(3) from aqueous sample under strongly alkaline (pH > 12, NaOH), chelated (EDTA) conditions into a recycled acidic acceptor stream. The acceptor is then injected onto an ion chromatograph where NH(3) and the MAs are fully resolved as their cations and detected conductimetrically. A versatile PC interfaced control unit and data capture unit (DCU) are employed in series to direct the selonoid valve switching sequence, IC operation and collection of data. Automation, together with other modifications improved both linearily (R(2) > 0.99 MAs 0-100 nM, NH(3) 0-1000 nM) and precision (",

author = "Gibb, {Stuart l} and Wood, {J W} and R Fauzi and C Mantoura",

note = "M1 - Article",

year = "1995",

month = may,

doi = "10.1155/S1463924695000320",

language = "English",

volume = "17",

pages = "205--212",

journal = "The Journal of automatic chemistry",

issn = "0142-0453",

publisher = "Taylor and Francis Ltd.",

number = "6",

}

TY - JOUR

T1 - Automation of flow injection gas diffusion-ion chromatography for the nanomolar determination of methylamines and ammonia in seawater and atmospheric samples

AU - Gibb, Stuart l

AU - Wood, J W

AU - Fauzi, R

AU - Mantoura, C

N1 - M1 - Article

PY - 1995/5

Y1 - 1995/5

N2 - The automation and improved design and performance of Flow Injection Gas Diffusion-Ion Chromatography (FIGD-IC), a novel technique for the simultaneous analysis of trace ammonia (NH(3)) and methylamines (MAs) in aqueous media, is presented. Automated Flow Injection Gas Diffusion (FIGD) promotes the selective transmembrane diffusion of MAs and NH(3) from aqueous sample under strongly alkaline (pH > 12, NaOH), chelated (EDTA) conditions into a recycled acidic acceptor stream. The acceptor is then injected onto an ion chromatograph where NH(3) and the MAs are fully resolved as their cations and detected conductimetrically. A versatile PC interfaced control unit and data capture unit (DCU) are employed in series to direct the selonoid valve switching sequence, IC operation and collection of data. Automation, together with other modifications improved both linearily (R(2) > 0.99 MAs 0-100 nM, NH(3) 0-1000 nM) and precision (

AB - The automation and improved design and performance of Flow Injection Gas Diffusion-Ion Chromatography (FIGD-IC), a novel technique for the simultaneous analysis of trace ammonia (NH(3)) and methylamines (MAs) in aqueous media, is presented. Automated Flow Injection Gas Diffusion (FIGD) promotes the selective transmembrane diffusion of MAs and NH(3) from aqueous sample under strongly alkaline (pH > 12, NaOH), chelated (EDTA) conditions into a recycled acidic acceptor stream. The acceptor is then injected onto an ion chromatograph where NH(3) and the MAs are fully resolved as their cations and detected conductimetrically. A versatile PC interfaced control unit and data capture unit (DCU) are employed in series to direct the selonoid valve switching sequence, IC operation and collection of data. Automation, together with other modifications improved both linearily (R(2) > 0.99 MAs 0-100 nM, NH(3) 0-1000 nM) and precision (

U2 - 10.1155/S1463924695000320

DO - 10.1155/S1463924695000320

M3 - Article

SN - 0142-0453

VL - 17

SP - 205

EP - 212

JO - The Journal of automatic chemistry

JF - The Journal of automatic chemistry

IS - 6

ER -

Automation of flow injection gas diffusion-ion chromatography for the nanomolar determination of methylamines and ammonia in seawater and atmospheric samples

Abstract

Access to Document

Fingerprint

Cite this